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White Oak Test Kit MSDS
1. Product Identification & Company Information
Substance or preparation trade name:
WOODWISE White Oak Test Kit Reagent A
Primary Use: Testing oak boards to determine if white oak is present.
Chemical Identity: Water mixture containing sodium nitrite
Supplier:
Design Hardwood Products, Inc.
15060 N.E. 95th St.
Redmond, WA 98052
Telephone: 425-869-0859
Fax: 425-881-2704
Revision Date: February 1, 2007
2. Composition and Information on Ingredients
CAS
No. |
Substance |
% By Weight |
7632-00-0 |
Sodium
Nitrite
|
5 - 15% |
7732-18-5 |
Water |
85
– 95% |
Toxicological Data on
Ingredients:
Sodium
Nitrite: ORAL (LD50):
Acute: 85 mg/kg (rat) 175 mg/kg (mouse)
DUST (LC50):
Acute: 5.5 ppm [5500 mg/m3] (Rat) 4
hours
3. Hazards Identification
EMERGENCY OVERVIEW:
Contains white to slightly yellow crystalline solid. Toxic if swallowed or dust is inhaled. Oxidizer: May ignite organic materials and react with other materials. Can decompose if mixed with acids or exposed to fire conditions, releasing toxic nitrogen oxides.
Potential Health
Hazards:
Skin: Prolonged contact with dust may cause irritation.
Eyes:
May cause temporary irritation.
Inhalation:
Dust may irritate nose and throat. Dusts are soluble and inhalation may result in toxic effects similar to ingestion.
Ingestion:
May irritate mouth, esophagus and stomach. Although small quantities are used in food preparation, swallowing moderate amounts of sodium nitrite can result in serious toxic effects including death. Sodium nitrite interferes with the blood's ability to transport oxygen.
Delayed Effects:
Sodium nitrite has no known delayed effects. (If sodium nitrite is used with amines found in certain cutting fluids, potentially carcinogenic nitrosamine compounds may be formed.)
Ingredients found on one of the three OSHA designated carcinogen lists are listed below:
INGREDIENT NAME NTP STATUS ARC STATUS OSHA LIST
No ingredients listed in this section.
4. First Aid Measures
EMERGENCY & FIRST AID PROCEDURES:
Skin: Wash with plenty of soap and water to remove all product residues. Remove contaminated clothing and wash before reuse.
Eyes: Immediately flush with running water continuing for 15 minutes. If irritation persists, consult physician.
Inhalation: Remove to fresh air. If breathing has stopped, give artificial respiration, preferably mouth to mouth. If breathing is difficult, oxygen should be administered, provided a qualified operator is present. Get immediate medical assistance for any symptom.
Ingestion: If conscious, give victim 2 to 4 glasses of water and induce vomiting by touching finger to back of throat. Continue until vomited fluid is clear. Get immediate medical assistance.
Advice to Physician: Sodium nitrite forms methemoglobin in the blood stream. Treat accordingly.
5. Fire & Explosion Hazards
FLAMMABLE PROPERTIES
Auto-Ignition Temperature: Not applicable
Flash Point: Not applicable
Flash Point Method: Not applicable
Upper Flame Limit (volume % in air): Not applicable
Lower Flame Limit (volume % in air): Not applicable
Flame Propagation Rate (solids): Not applicable
OSHA Flammability Class: Not applicable
Extinguishing Media: Use flooding amounts of water or other agents. DO NOT use dry chemicals containing ammonium phosphate.
Unusual Fire and Explosion Hazards: Material does not burn but is an oxidizing agent and will support combustion of other materials. Product decomposes about 608oF releasing toxic nitrogen oxides.
Special Fire-Fighting Precautions/Instructions: Wear self-contained breathing apparatus.
6. Accidental Release
In case of spill or other release:
(See Section 8 for recommended personal protective equipment.) Sweep or shovel spilled material into containers. Close container and label them. Do not allow product or residues to enter waterways and/or any source of drinking water.
Spills and releases may have to be reported to Federal and/or local authorities. See Section 15 regarding reporting requirements.
7. Handling & Storage
Normal Handling:
(See Section 8 for recommended personal protective equipment.) Avoid contact with skin and eyes. Do not breathe product dusts. Avoid contact with combustible materials and acids.
Storage Recommendations:
Store in a cool, dry place. Keep container closed. Do not store on wooden floors. Isolate from combustible materials.
8. Exposure Controls/Personal Protection
Engineering Controls:
Use local exhaust ventilation in any areas where product dusts may be generated. (Note incompatibilities in Section 10.)
PERSONAL PROTECTIVE EQUIPMENT:
Skin Protection: Use impervious gloves (e.g. rubber) for routine handling. Wear long sleeved shirt and pants. Impervious work aprons may be required for transfer of material from packages to process equipment.
Eye Protection: Wear safety goggles in any area where dusty conditions may occur.
Respiratory Protection: Not required for properly ventilated areas.
Additional Recommendations: Provide eyewash and washing facilities.
EXPOSURE GUIDELINES:
INGREDIENT NAME ACGIH TLV OSHA PEL OSHA LIST Other Limits
No ingredients listed in this section.
OTHER EXPOSURE FOR POTENTIAL DECOMPOSITION PRODUCTS:
None.
9. Physical & Chemical Characteristics
Appearance: Clear to slightly yellow liquid
Physical State: Solution
Molecular Weight:69.0
Chemical Formula: NaNO2
Odor: None
Specific Gravity: 2.168 (Water = 1)
Solubility in Water (weight%): 46% at 68oF
pH (1% solution/water): Approximately 9 (for aqueous solution)
Boiling Point: Decomposes at above 320o C or 608 o F
Melting Point: 271o C (519.8 o F)
Vapor Pressure: Not applicable
Vapor Density (air = 1.0): Not applicable
Evaporation Rate: Not applicable
Volatility: Not applicable
% Volatiles: Not applicable
Flash Point: Non flammable
(Flash point method and additional flammability data are found in Section 5.)
10. Stability
Normally Stable? (Conditions to Avoid):
Normally stable.
Incompatibilities:
Hazardous reactions can occur with acids, ammonium compounds, reducing agents (particularly cyanides, thiocyanates and thiosulfates). May ignite organic compounds and other combustible materials.
Hazardous Decomposition Products:
Oxides of nitrogen (toxic and irritating).
Hazardous Polymerization:
Will not occur.
11. Toxicological Information
Immediate (Acute) Effects:
LD50 (oral, rat) 180 mg/kg
LD50 (oral, rabbit) 186 mg/kg
Eye irritation, rabbit 500 mg/24 hr; mild
Delayed (Sub-chronic and chronic) Effects:
Multiple reproductive tests indicate that sodium nitrite is not teratogenic. Fetal toxicity has been demonstrated in pregnant animals fed toxic doses of sodium nitrite. This is due to the formation of methemoglobin.
Other Data:
None.
12. Ecological Information
17.1 ppm/24 hr/minnow/no effect/fresh water
7.5 ppm/48 hr/mosquito fish/TLm/fresh water
13. Disposal Considerations
RCRA
Is the unused product a RCRA hazardous waste if discarded? Yes
If yes, the RCRA ID number is: D001 (ignitable)
OTHER DISPOSAL CONSIDERATIONS:
The information offered in Section 13 is for the product as shipped. Use and/or alterations to the product such as mixing with other materials may significantly change the characteristics of the material and alter the RCRA classification and the proper disposal method.
14. Transport Information
US DOT Hazard Class: 5.1 Oxidizer (6.1 Toxic subsidiary risk)
US DOT ID Number: UN1500
Proper Shipping Name: Sodium Nitrite
For additional information on shipping regulations affecting this material, contact the information number found in Section 1.
15. Regulatory Information
TOXIC SUBSTANCES CONTROL ACT (TSCA)
TSCA Inventory Status: Listed on TSCA Inventory of Chemical Substances
Other TSCA Issues: Requires export notification (Section 12b). Subject to SNUR if used in metalworking fluids (40CFR721.4740).
SARA TITLE III/CERCLA
Reportable Quantities (RQ's) and/or "Threshold Planning Quantities" (TPQ's) exist for the following ingredients.
INGREDIENT NAME SARA/CERCLA RQ (lb) SARA EHS TPQ (lb)
Sodium Nitrite 100 None
Spills or releases resulting in the loss of any ingredient at or above its RQ requires immediate notification to the National Response Center (800) 424-8802, and to your local emergency planning committee.
Lists
SARA: Extremely hazardous substance – No
CERCLA hazardous substance – Yes
SARA Toxic Chemical – Yes
Canadian WHMIS Classification– C: D-1B: D-2B
INPCA – HMIS Ratings
Health (Acute): 2 chronic
Flammability: 0
Reactivity: 1
Personal protection: varies
California, Pennsylvania, Massachusetts, New Jersey Right-to-Know
Hazardous Substance List
Sodium Nitrite
California Proposition 65
To the best of our knowledge, this product contains no levels of listed substances which the state of California has found to cause birth defects or other reproductive effects.
California No Significant Risk Level
The chemicals in this product are not listed.
CWA
CAS #7632-00-0 is listed as a hazardous substance
Section 311 Hazard Class:
Immediate
SARA 313 Toxic Chemicals
The following ingredients are SARA 313 "Toxic Chemicals" and may be subject to annual reporting requirements. CAS numbers and weight percents are found in Section 2.
Ingredient Name: Sodium Nitrite≉ Comment: None
State Right-to-Know
In addition to the ingredients found in Section 2, the following are listed for state right-to-know purposes.
Ingredient Name: No ingredients listed in this section.
Additional Regularly Information
None
WHMIS Classification (Canada):
C, D1B, D2B
Foreign Chemical Control Inventory Status:
Listed on Canadian DSL and EU's EINECS (EINECS # 231-555-9)
16. Other Information
European/International Regulations
CAS # 7632-00-0 – European labeling in accordance with EC directives hazard symbols: TOXI
Risk phases:
R25 toxic if swallowed.
R8 contact with combustible material may cause fire.
R36/37/38 irritating to eyes, respiratory system and skin.
R34 causes burns.
Safety Phrases:
S45 in case of accident or if you feel unwell, seek medical advice immediately.
S26 in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39 wear suitable gloves and eye/face protection.
WGK (Water danger protection): CAS # 7632-00-0 : 2
Canadian:
CAS # 7632-00-0 is listed on Canada's DSL/NDSL list. This product has a WHMIS classification of C, D1B, D2B. It is not listed on Canada's ingredient disclosure list.
Other Disclosure Limits:
CAS # 7632-00-0: OEL Czechoslovakia – TWA 1 mg/m3 SEL 5 mg/m3
OEL Hungary: STEL 1 mg/m3 skin